Member countries are expected to provide the "widest possible assistance with respect to enquiries related to these individuals," according to a council statement.
The men charged are Manssor Arbabsiar, a dual U.S.-Iranian citizen, and Gholam Shakuri, an Iran-based member of Iran's Islamic Revolutionary Guard Corps. The alleged scheme was allegedly directed by the Quds Force, a branch of the Islamic Revolutionary Guard Corps.
The three others are Qasem Soleimani, Abdul Shahlai and Hamed Abdollahi. U.S. officials have called them "high-ranking" members of the Quds Force.
Britain also froze assets of the five men this week.
The Iranian Foreign Ministry has called the assassination-for-hire accusations baseless.
Authorities developed the case against the suspects with the help of an undercover informant posing as an associate of a Mexican drug cartel, according to officials and an FBI agent's affidavit released last week.
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